Sediment Phosphorus Chemistry and Microbial Biomass along a Lowland New Zealand Stream   总被引：1，自引：0，他引：1  

R. W. McDowell 《Aquatic Geochemistry》2003,9(1):19-40

An evaluation of the distribution of P concentrations in streamflow, P fractions andthe microbial biomass P pool was made of bed and bank sediments along a lowlandstream in New Zealand. Agricultural intensification increased downstream. However,most P fractions decreased downstream (total P decreased from c. 400 to 250 mg kg^-1) in bed sediments, while P in streamflow remained relatively constant (generally < 0.005 mg l^-1) and sediment microbial P increased from 2 to 8 mg kg^-1. An investigation of P release from dried and rewetted sediments showed that solution P (CaCl2-P) increased, on average > 300%, and proportional to the size of the microbial biomass P pool before drying, except in sediments with much organic carbon (OC). When supplied with a P source (1 mg l^-1) and then simultaneously with a C source (glucose, 100 mg l^-1), all sediment behaved similarly and biotic sorption accounted for, on average, 27 and 34% of the total sediment uptake, respectively (maximum of 58%). The quantity of P taken up was related to the initial size of the microbial biomass P pool, and the availability of P as influenced by organic P complexes and OC. The sediment microbial biomass represents a transient, but small store of P could be useful to indicate bioavailable P inputs.  相似文献   

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia     

Makoto Haruna    Takahiro Hanamuro    Kaoru Uyeda    Hirokazu Fujimaki  Hiroshi Ohmoto 《Resource Geology》2003,53(2):75-88

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.  相似文献   

热带森林生态系统气象观测铁塔的设计          下载免费PDF全文

刘玉洪  张克映  马友鑫  张建候 《气象》1997,23(5):41-43

讨论了西双版纳地区原始热带雨林和人工林气象观测铁塔的选择与设计，扼要地介绍了气象观测铁塔的塔形，结构及春功能，并提出了在高湿多雷热带雨林地区设计，安装铁塔应注意的事项及解决途径。  相似文献   

火焰原子吸收法间接测定磷矿中氯   总被引：2，自引：0，他引：2  

达刘生 《岩矿测试》1997,16(1):80-81

火焰原子吸收法间接测定磷矿中氯达刘生１云南个旧市化肥厂中心化验室个旧６６１４１１目前磷矿中Ｃｌ－含量的测定多采用浊度法、氯离子选择电极法及离子色谱法。本文采用火焰原子吸收法来间接测定磷矿中Ｃｌ－，即在试样溶液中加入定量的Ａｇ＋，试样中Ｃｌ－与Ａｇ＋生...  相似文献   

痕量铁和锰的化学发光检测   总被引：5，自引：1，他引：5  

周延秀  朱果逸 《岩矿测试》1997,16(3):221-228

评述了国内外有关铁、锰的化学发光分析进展。从发光体系、操作方式、最佳条件、干扰离子、检测限等各个方面对化学发光法测定铁、锰及其它们与其它组分同时测定中的应用进行分类评述。  相似文献   

榴辉岩中铁铝榴石的测定方法研究   总被引：3，自引：1，他引：3  

黄宝贵  柳建春 《岩矿测试》1997,16(4):241-244254

对国内主要矿区铁铝石榴子石纯矿物中铁的价态规律进行了研究。证明其所含Ｆｅ均以Ｆｅ＾２＋为主，其质量分数在８３－９４，并将Ｆｅ＾２＋这特征性成分用于某地榴辉岩中铁铝榴石的间接测定，获得结果与焙烧磁化－磁选法一致且精度好，较磁化法简便，快速。  相似文献   

海洋中磷的循环与沉积作用   总被引：1，自引：1，他引：1  

东野脉兴 《化工矿产地质》1996,18(3):191-195

磷在海洋中的循环与沉积主要是靠生物作用进行的。海洋表层水中的溶解磷几乎全部被海洋植物摄取，海洋植物及动物死亡后最终以生物碎屑的形式沉入海底，在其沉降和到达深层水的过程中大部分被分解、破坏，变成可溶组分又重新返回海水，使深层水中磷浓度提高。含磷浓度高的深层水被上升洋流带到表层后又被生物吸收，重复循环。当上升洋流抵达大陆边缘，特别是遇有陆缘坻存在时，磷等营养物质滞留，导致磷质生物大量繁衍，死亡后沉积，并经成岩作用，便形成大规模的工业磷块岩矿床  相似文献   

低温条件下有机酸对铁、铜的淋滤实验研究     

张海祥  王玉荣  梅厚钧 《矿床地质》1997,16(1):86-92

水／岩作用实验研究表明，在低温条件下柠檬酸、草酸和酒石酸对岩石中的铁、铜都有很高的淋滤率。这表明，在表生地质作用过程中有机酸对成矿元素有很强的活化能力。实验研究同时发现，有机酸对成矿元素的活化能力受其分解温度的限制，由于大部分有机酸的分解温度都在２５０℃以下，因而有机酸对成矿元素的活化仅限于低温条件。本次研究还显示，判断一种岩石能否成为矿源层，不能简单的以其中成矿元素的含量高低作为标准，其中更关键的因素是元素在岩石中的存在形式，如果成矿元素在岩石中难以活化的形式存在，那么含量再高也无法提供成矿物质  相似文献   

西昆仑山南侧甜水海湖岩芯铁变化的环境记录   总被引：11，自引：0，他引：11  

余素华  李世杰 《地球化学》1997,26(6):88-98

阐述了青藏高原西昆仑山南侧甜水海湖岩芯沉积物中氧化铁的丰度、频率分布和富集系数的变化规律。其丰度值范围FeO0．39％-3.95％，平均值为1．25％；Fe2O30．44％－8．09％，平均值为2．60％；Fe2O3／FeO0．21－3．60，平均比值1．12。说明该彻岩芯沉积物中铁平均丰度值较低，但其变化幅度较宽且清楚，在一定程度上反映了古气候环境具有较大幅度的波动。变异系数值表明，该湖岩芯沉积物中FeO的离散程度较Fe2O3大。大约距今23万年来氧化铁的沉积地球化学特征可划分出7个环境演化阶段，并基本上可与深海氧同位索阶段对比。揭示了甜水海湖演化与青藏高原强烈隆升引起的气候环境改变的密切关系。在距今23一15万年，沉积以河流相或冲积、洪积相为主，沉积环境以氧化环境为主导，气候以温干型波动；在距今15－7．4万年，沉积以湖相为主，沉积环境以还原环境为主导，气候以温湿型为主；在距今74万年以来，湖盆沉积环境多样化，沉积物以湖相和近源冲积、洪积相交替出现。气候出现冷湿、冷干、温湿和温干多种波动模式。这些资料分析初步认为甜水海古湖大约形成于距今15万年，即青藏高原第三成湖期，这也与青藏高原在距今15万年左右的再次构造隆升有关。  相似文献   

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea     

C.A McCammon  T Stachel 《Earth and Planetary Science Letters》2004,222(2):423-434

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.  相似文献